The synthesis of the Fe 3 O 4 nanoparticles and the analysis of the current-voltage measurements on Au/Fe 3 O 4 /p-Si schottky contacts in a wide temperature range


DENİZ A. R., Çaldıran Z., ŞAHİN Y., Şinoforoğlu M., Metin Ö., Meral K., ...Daha Fazla

Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science, cilt.44, sa.8, ss.3809-3814, 2013 (SCI-Expanded) identifier

Özet

The iron oxide (Fe 3 O 4 ) magnetic nanoparticles were synthesized via the organic solution phase method and used for the fabrication of the Au/Fe 3 O 4 /p-Si rectifying device. The variation in electrical characteristics of the Au/Fe 3 O 4 /p-Si Schottky contacts was investigated as a function of temperature using current-voltage (I-V) measurements in the temperature range of 40 K to 370 K (-233 C to 97 C). The I-V characteristics of the contacts indicated extremely strong temperature dependence. The double distribution of barrier heights was found in the Fe 3 O 4 /p-Si Schottky diodes from the I-V-T measurements. The Schottky barrier height (Φ b ) increases with the increasing temperature, while the ideality factor n decreases. The nonlinearity in the activation energy plot was observed, which is attributed to barrier inhomogeneities by assuming a Gaussian distribution of barrier heights at the Fe 3 O 4 /p-Si interface. The Richardson constant measured from the temperature-dependent I-V characteristics is 2.99 A/K 2 cm 2 , which is lower than the ideal value. © 2013 The Minerals, Metals & Materials Society and ASM International.