The effects of various boron compounds on the thermal, microstructural and mechanical properties of PLA biocomposites


AVCI A., AKDOĞAN EKER A., BODUR M. S., KÜÇÜKYILDIRIM B. O.

Thermochimica Acta, vol.731, 2024 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 731
  • Publication Date: 2024
  • Doi Number: 10.1016/j.tca.2023.179656
  • Journal Name: Thermochimica Acta
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Analytical Abstracts, Aquatic Science & Fisheries Abstracts (ASFA), Biotechnology Research Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, INSPEC, Metadex, Civil Engineering Abstracts
  • Keywords: Biocomposite, Flame retardancy, Injection moulding, Mechanical properties
  • Hakkari University Affiliated: Yes

Abstract

This study aims to understand how ulexite, boric acid-borax mixtures (1:1), and zinc borate fillers affect the thermal and mechanical properties of the poly (lactic acid) (PLA). For this purpose, three different boron fillers were added to the PLA matrix at four different concentrations of 3 %, 5 %, 8 %, and 12% wt. UL-94 test was conducted to comprehend the impacts of boron fillers on the fire resistance of the biocomposites. Thermogravimetric analysis was applied to determine the thermal stability, mass loss, and decomposition temperature of the samples. The biocomposite's significant mechanical properties, such as tensile strength, flexural strength, Young's modulus, and elongation at break, were assessed using tensile and three-point bending tests. Although the tensile and flexural strengths of PLA reduced, flexural and Young's modulus rose by roughly 20 % and 22 %, respectively, with rising boron filler rates.